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Just any painless method.
Originally, my favorite was inert gas asphyxiation. Based on previously found info, it seemed like the best option, just falling asleep and dying. Of course I was aware of the main risk: running out of the inert gas and again getting oxygen. That could result in permanent severe brain damage.
However I later found even worse stuff. Veterinarians apparently stopped using this method as the animals were showing severe signs of distress, meaning that it perhaps wouldn't be as painless.
Finally, there was a nitrogen hypoxia execution in Alabama recently:
Source: AP News
Thus I finally ruled this out.
Yeah, maybe don't take the utterly sadistic version designed by cruel people for maximum suffering, as a reference for how things normally work.
The only legal solution to commit assisted suicide, in Switzerland, uses nitrogen hypoxia for a reason.
As a matter of fact, the founder of exit international even flew to Florida before Christmas, as an attempt to stop the execution. Coming from a fervent supporter of people's right "to be able to plan for the end of their life in a way that is reliable, peaceful & at a time of their choosing", that should tell you everything you need to know about the execution. It was made horrible, purposely.