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Just any painless method.
Originally, my favorite was inert gas asphyxiation. Based on previously found info, it seemed like the best option, just falling asleep and dying. Of course I was aware of the main risk: running out of the inert gas and again getting oxygen. That could result in permanent severe brain damage.
However I later found even worse stuff. Veterinarians apparently stopped using this method as the animals were showing severe signs of distress, meaning that it perhaps wouldn't be as painless.
Finally, there was a nitrogen hypoxia execution in Alabama recently:
Source: AP News
Thus I finally ruled this out.
They fucked it up, he held his breath and caused himself pain because of course he didn't want to die and it's barbaric to kill people. But also, those spams that happened are after you have already lost consciousness