I think I also had this issue using Cinnamon once, but then I just used VLC instead. Never bothered to look into why. Worked fine in GNOME for me though.
I found a thread with a similar issue: https://forums.opensuse.org/t/flatpak-mpv-broken-since-20240306-snapshot/172981
There it seems the issue was audio. Try running the flatpak version with flatpak run io.mpv.Mpv --ao=pulse path-to-your-media-file
Appending
(intext:“modlog” & “instances” & “docs” & “code” & “join lemmy”)
to your search query will search most instances. Works with Google, Startpage, SearXNG afaik.