How are your backups currently stored, simple copies of the files like you would make with rsync? I assume your on a Linux NAS, in which case fdupes would likely fit the bill. meld would be another option, and it also has a GUI if your NAS isn't headless.
For future backups restic might be a nice option as it deduplicates itself each time you run the backup. You can set retention policies (i.e. 7 daily, 4 weekly, 2 monthly, etc...) that only keep regulated intervals of backups.